1. komponenta

Lecture type	Total
Lectures	45
Laboratory exercises	45

* Load is given in academic hour (1 academic hour = 45 minutes)

COURSE OBJECTIVE: The course aims to provide basic knowledge about the analysis of materials; from sampling, method selection, to interpretation of the obtained results.

COURSE PROGRAM:
Week 1: The role of analytical chemistry in material analysis. Basics of analytical process. Sources of errors in chemical analysis. Systematic and random errors, outliers. Statistical evaluation of measurement results. Accuracy. Precision.
Week 2: Sample and sampling. Representative sample. Sampling plan. Sub-sampling. Semple preparation for chemical analysis. Water in solid samples. Digestion of solid samples.
Week 3: Chemical equilibria. Homogeneous and heterogeneous equilibria. Equilibrium constants.
Week 4: Gravimetric methods of analysis: Mass measurement. Type of precipitate. Precipitate formation. Factors affecting precipitate formation. Precipitate purity.
Week 5: Introduction to titrimetric methods of analysis. Volume measurement. Standard solutions. Indicators. Titration curve.
Week 6: Titrimetric methods: Neutralization titrations. Neutralization titration curves. Selection of indicators.
Week 7: First test.
Week 8: Titrimetric methods: Precipitation titrations. Precipitation titration curve. Selection of indicators. Complexometric titrations. Complexometric titration curve. Selection of indicators.
Week 9: Titrimetric methods: Redox titrations. Redox titration curve. Selection of indicators.
Week 19: Electroanalytical methods: Electrogravimetry. Potentiometric titrations. Indicator and reference electrodes.
Week 11: Introduction to spectrophotometric methods of analysis. Beerov low. Calibration. Calibration curve.
Week 12: Separation and isolation of analytes. Selective precipitation.
Week 13: Liquid-liquid extraction. Liquid-liquid extraction of weak acids. Liquid-liquid extraction of metal ions.
Week 14: Chromatography. Chromatographic system. Chromatographic techniques. Chromatogram. Chromatographic resolution.
Week 15: Second test

PREREQUISITES FOR COURSE ENROLLMENT:
Attended lectures and completed exercises for the course General Chemistry.

PREREQUISITES FOR TAKING THE EXAM:
Attendance at lectures, successfully completed laboratory exercises, passed the laboratory exercises test.

DEVELOPMENT OF GENERAL AND SPECIFIC COMPETENCIES OF STUDENTS:
General knowledge in the field of natural sciences (analytical chemistry) and specific knowledge of material analysis with special emphasis on team and individual work are being developed.

STUDENT OBLIGATIONS:
Regular class attendance (lectures and laboratory exercises).
TEACHING METHODS:
Lectures
Laboratory exercises
Consultations as needed

METHODS OF KNOWLEDGE ASSESSMENT:
Laboratory exercises test
Continuous knowledge assessment (two tests), depending on the achieved results, it is possible to be exempted from taking the exam
Written exam
Oral exam

METHOD OF MONITORING THE QUALITY AND PERFORMANCE OF COURSES:
Student survey

COURSE LEARNING OUTCOMES
1. Understand a systematic approach to chemical analysis
2. Create a sampling plan in order to obtain a representative sample
3. Apply chemical laws for the purpose of identification, separation and quantification of analytes in real samples
4. Propose an appropriate method of separation and isolation of analytes from a real sample
5. Critically compare methods of quantitative chemical analysis
6. Identify the causes of errors in chemical analysis
7. Analyse a real sample using an appropriate chemical analysis method
8. Review the validity of the results of chemical analysis using statistical tests

LEARNING OUTCOMES AT THE PROGRAM LEVEL TO WHICH THE COURSE CONTRIBUTES
1. Explain scientific principles important for materials science and engineering, especially in chemistry, physics, mathematics and chemical engineering
2. Define simple problems in area of materials science and engineering in order to solve them
3. Analyse materials using chemical and physical techniques and various laboratory equipment and instruments
4. Theoretically explain result of experimental work
5. Organise efficient laboratory work, whether independently or as a part of a multidisciplinary team
6. Present results of their work in written and oral form

REQUIRED LITERATURE:
1. Z. Šoljić, M. Kaštelan-Macan, Analitička kemija: Volumetrija, Fakultet kemijskog inženjerstva i tehnologije, Zagreb, 2002.
2. Z. Šoljić, Kvalitativna kemijska analiza anorganskih tvari, Fakultet kemijskog inženjerstva i tehnologije, Zagreb, 2003.
3. M. Kaštelan-Macan, Analitička kemija, I dio (Gravimetrija), Sveučilište Zagreb, 1991.
4. D. A. Skoog, D. M. West, F. J. Holler, Osnove analitičke kemije, Školska knjiga, Zagreb, 1999.
5. M. Kaštelan-Macan, Kemijska analiza u sustavu kvalitete, Školska knjiga, Zagreb 2003.
6. D. Harvey, Modern analytical chemistry, McGraw-Hill, Boston 2000.
7. Nj. Radić, L. Kukoč Modun, Uvod u analitičku kemiju, Školska knjiga, d. d., Zagreb, 2017.

1. Analitička kemija: Volumetrija, Z. Šoljić, M. Kaštelan-Macan, Fakultet kemijskog inženjerstva i tehnologije, Zagreb, 2002.
2. Kvalitativna kemijska analiza anorganskih tvari, Z. Šoljić, Fakultet kemijskog inženjerstva i tehnologije, Zagreb, 2003.
3. Analitička kemija, I dio (Gravimetrija), M. Kaštelan-Macan, Fakultet kemijskog inženjerstva i tehnologije, Zagreb, 1991.
4. Osnove analitičke kemije, D. A. Skoog, D. M. West, F. J. Holler, Školska knjiga, Zagreb, 1999.
5. Kemijska analiza u sustavu kvalitete, M. Kaštelan-Macan, Školska knjiga, Zagreb, 2003.
6. Modern analytical chemistry, D. Harvey, McGraw-Hill, Boston, 2000.
7. Uvod u analitičku kemiju, Nj. Radić, L. Kukoč Modun, Školska knjiga, Zagreb, 2017.

Mandatory course - Regular studij - Materials Science and Engineering