AIM OF THE COURSE:
Understanding of fundamental laws and theories of physical chemistry which are applied in chemical-engineering practice. Developing the ability to logically solve problems and derive equations.
SYLLABUS:
1. Introduction: Phase states of matter, Ideal gas-equation of state.
2. Kinetic-molecular theory, velocity and energy of gas molecules, Maxwell-Boltzmann' s Law.
3. Real gases-equations of state, liquefaction.
4. First colloquium/midterm exam
5.Thermodynamics: heat and work, First Law, internal energy, enthalpy, heat capacities.
6. Thermochemistry: Hess' Law, Kirchhoff's Law. Adiabatic processes.
7. Spontaneity of process and equilibrium, Carnot cycle, Second Law of thermodynamics, entropy, reversibility of process.
8. Gibbs energy, Third Law of thermodynamics, Dependence of Gibbs energy on temperature and pressure, Fugacity.
9. Second colloquium/midterm exam
10. Mixtures: ideal and nonideal, chemical potential, Gibbs-Duhem equation.
11. Phase equilibria, Clapeyron equation, Clausius- Clapeyron equation, triple point, phase rule.
12. Rauolt's Law, colligative properties of mixtures, Henry's Law.
13. Distillation, vapor pressure diagrams, boiling point diagrams.
14. Fundamentals of phase equilibria of three-component systems, distribution law, crystallization, osmotic equilibrium.
15. Third colloquium/midterm exam
Laboratory:
1. Determination of molecular mass of ideal gass.
2. Calorimetry. Determination of heat of reaction.
3. Cryoscopy.
4. Boiling point diagram.
5. Nernst distribution law.
PREREQUISITES FOR COURSE ENROLLMENT:
Passed courses: Mathematics II, General and inorganic chemistry
PREREQUISITES FOR TAKING THE EXAM:
Passed courses: General and inorganic chemistry
DEVELOPING GENERAL AND SPECIFIC COMPETENCIES OF STUDENTS:
Ability to solve quantitative problems. Conducting complex experiments and processing of measured data.
STUDENTS ' TEACHING OBLIGATIONS AND THEIR PERFORMANCE:
Attending lectures and laboratory exercises.
TEACHING METHODS:
lectures (ex cathedra)
seminar
laboratory exercises (work in group under supervision of assistant or demonstrator)
consultatitons as needed
KNOWLEDGE TESTS AND EXAMINATION:
entrance colloquium from laboratory exercise
written or oral colloquium from laboratory exercise
three written knowledge tests during the semester (allow exemption from written and oral exams)
written exam (three numerical problems, need 50% points to pass)
oral exam
MONITORING OF QUALITY AND COURSE PERFORMANCE:
student survey
COURSE LEARNING OUTCOMES:
1.describe fundamental laws of physical chemistry related to gasses, thermodynamics and phase equilibria
2.apply knowledge of mathematics and derive equations
3.prepare and do laboratory experiments
4.analyze and interpret the experimental results
5.prepare laboratory reports
LEARNING OUTCOMES AT THE PROGRAMME LEVEL:
1. describe the phenomena in the field of chemical engineering using vocabulary and apparatus of the fundamental sciences- mathematics, physics and chemistry
2. define chemical engineering problems, which includes their analysis and formulation in order to solve them using fundamental principles
3. interpret results of independently planned experiments, with guidance of a senior chemical engineer
4. demonstrate effective communication skills, both in writing and presentation, including English, and capability of working effectively in teams that may involve professionals from other disciplines
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P. Atkins, J. de Paula, Atkin's Physical Chemistry, 8th edition, Oxford University Press, Oxford 2006.,
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R. Brdička, Osnove fizikalne kemije, Školska knjiga, Zagreb, 1969.,
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W. J. Moore, Physical Chemistry, Longman group Ltd, London 1974,
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