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Physical chemistry I
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Physical chemistry I
Code: 143334
ECTS: 6.0
Lecturers in charge: prof. dr. sc. Marica Ivanković
prof. dr. sc. Jelena Macan
Lecturers: prof. dr. sc. Jelena Macan - Seminar

dr. sc. Silvia Morović - Laboratory exercises
dr. sc. Andreja Žužić - Laboratory exercises
Take exam: Studomat
Load:

1. komponenta

Lecture typeTotal
Lectures 45
Laboratory exercises 30
Seminar 15
* Load is given in academic hour (1 academic hour = 45 minutes)
Description:
AIM OF THE COURSE:
Understanding of fundamental laws and theories of physical chemistry which are applied in chemical-engineering practice. Developing the ability to logically solve problems and derive equations.
SYLLABUS:
1. Introduction: Phase states of matter, Ideal gas-equation of state.
2. Kinetic-molecular theory, velocity and energy of gas molecules, Maxwell-Boltzmann' s Law.
3. Real gases-equations of state, liquefaction.
4. First colloquium/midterm exam
5.Thermodynamics: heat and work, First Law, internal energy, enthalpy, heat capacities.
6. Thermochemistry: Hess' Law, Kirchhoff's Law. Adiabatic processes.
7. Spontaneity of process and equilibrium, Carnot cycle, Second Law of thermodynamics, entropy, reversibility of process.
8. Gibbs energy, Third Law of thermodynamics, Dependence of Gibbs energy on temperature and pressure, Fugacity.
9. Second colloquium/midterm exam
10. Mixtures: ideal and nonideal, chemical potential, Gibbs-Duhem equation.
11. Phase equilibria, Clapeyron equation, Clausius- Clapeyron equation, triple point, phase rule.
12. Rauolt's Law, colligative properties of mixtures, Henry's Law.
13. Distillation, vapor pressure diagrams, boiling point diagrams.
14. Fundamentals of phase equilibria of three-component systems, distribution law, crystallization, osmotic equilibrium.
15. Third colloquium/midterm exam

Laboratory:
1. Determination of molecular mass of ideal gass.
2. Calorimetry. Determination of heat of reaction.
3. Cryoscopy.
4. Boiling point diagram.
5. Nernst distribution law.

PREREQUISITES FOR COURSE ENROLLMENT:
Passed courses: Mathematics II, General and inorganic chemistry

PREREQUISITES FOR TAKING THE EXAM:
Passed courses: General and inorganic chemistry

DEVELOPING GENERAL AND SPECIFIC COMPETENCIES OF STUDENTS:
Ability to solve quantitative problems. Conducting complex experiments and processing of measured data.

STUDENTS ' TEACHING OBLIGATIONS AND THEIR PERFORMANCE:
Attending lectures and laboratory exercises.

TEACHING METHODS:
lectures (ex cathedra)
seminar
laboratory exercises (work in group under supervision of assistant or demonstrator)
consultatitons as needed

KNOWLEDGE TESTS AND EXAMINATION:
entrance colloquium from laboratory exercise
written or oral colloquium from laboratory exercise
three written knowledge tests during the semester (allow exemption from written and oral exams)
written exam (three numerical problems, need 50% points to pass)
oral exam

MONITORING OF QUALITY AND COURSE PERFORMANCE:
student survey

COURSE LEARNING OUTCOMES:
1.describe fundamental laws of physical chemistry related to gasses, thermodynamics and phase equilibria
2.apply knowledge of mathematics and derive equations
3.prepare and do laboratory experiments
4.analyze and interpret the experimental results
5.prepare laboratory reports
LEARNING OUTCOMES AT THE PROGRAMME LEVEL:
1. describe the phenomena in the field of chemical engineering using vocabulary and apparatus of the fundamental sciences- mathematics, physics and chemistry
2. define chemical engineering problems, which includes their analysis and formulation in order to solve them using fundamental principles
3. interpret results of independently planned experiments, with guidance of a senior chemical engineer
4. demonstrate effective communication skills, both in writing and presentation, including English, and capability of working effectively in teams that may involve professionals from other disciplines
Learning outcomes:
Literature:
  1. P. Atkins, J. de Paula, Atkin's Physical Chemistry, 8th edition, Oxford University Press, Oxford 2006.,
  2. R. Brdička, Osnove fizikalne kemije, Školska knjiga, Zagreb, 1969.,
  3. W. J. Moore, Physical Chemistry, Longman group Ltd, London 1974,
Prerequisit for:
Enrollment :
Passed : Calculus II
Passed : General and inorganic chemistry

Examination :
Passed : General and inorganic chemistry
3. semester
Mandatory course - Regular studij - Chemical Engineering
Consultations schedule:
  • prof. dr. sc. Jelena Macan:

    Available on previous arrangement (e-mail). Answers within 24 h, possibly longer over the weekends.

    Location:
  • prof. dr. sc. Jelena Macan:

    Available on previous arrangement (e-mail). Answers within 24 h, possibly longer over the weekends.

    Location:
  • dr. sc. Andreja Žužić:

    By agreement, prior notice via email is required.

    Location: