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Physical chemistry II
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Physical chemistry II
Code: 32055
ECTS: 7.0
Lecturers in charge: prof. dr. sc. Davor Dolar
Take exam: Studomat
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1. komponenta

Lecture typeTotal
Lectures 45
Laboratory exercises 30
* Load is given in academic hour (1 academic hour = 45 minutes)
Description:
COURSE OBJECTIVE
Physical chemistry is an essential natural science in the field of materials, so understanding and applying the basic principles, laws and theories of physical chemistry is crucial in materials science and engineering. The aim of the course is also to develop the ability to logically solve problems and derive equations closely related to materials.

THE CONTENTS OF THE COURSE
1. week: Description of chemical equilibrium (Gibbs energy minimum), thermodynamic equilibrium constant, Response of equilibrium to temperature (van t Hoff equation)to pressure
Seminar
2. week: Response of equilibrium to pressure, NH3 syntesis, Heterogeneous chemical equilibrium
Seminar, Introductory colloquium from laboratory exercises
3. week: Surface phenomena: surface tension, surface films
Laboratory exercise
4. week: Surface phenomena: adsorption, adsorption isotherms (Freundlich, Langmuir, B.ET.)
Seminar, Introductory colloquium from laboratory exercise
5. week: Conductivities of electrolyte solutions, weak electrolytes (Ostwald s dilution law)
First partial exam, Laboratory exercise
6. week: Conductivities of strong electrolyte solutions, (Debye Huckel theory and law)
Seminar, Laboratory exercise
7. week: Equilibrium electrochemistry, half reaction and electrodes, electrode potential
8. week: Galvanic cells, electromotive force, Nernst equation
Seminar, Laboratory exercise
9. week: Physical processes, Diffusion, Fick s first and second law of difusion
10. week: Rates of chemical reaction; definition, rate laws and rate constants, reaction order, and determination of rate law. The chemistry of stratospheric ozone ozone decomposition
Seminar, Laboratory exercise
11. week: Kinetics of complex reaction (reverse, parallel, and consecutive reactions)
Laboratory exercise
12. week: Kinetics of complex reations, chain reaction, explosion, polymerization kinetics
13. week: Kinetic and thermodynamic control of reactions, Temperature dependence of reaction rates
Seminar
14. week: Kinetics of reactions in liquids and on the surface. Catalysis, homogeneous catalysis, acid base catalysis, reaction retardation and inhibition, heterogeneous catalysis.
15. week: Second partial exam

DEVELOPING GENERAL AND SPECIFIC COMPETENCIES OF STUDENTS
Application of basic physicochemical laws that describe physicochemical phenomena in the world around us in solving problems in material science
and engineering.
1. chemical equilibria,
2. characterization and application of surface phenomena of surface tension and adsorption,
3. describing homogeneous and heterogeneous equilibria in electrolyte solutions,
4. understanding chemical kinetics,
5. understanding catalysis and the role of catalysts, and
6. Planning and conducting complex experiments and analytical and graphical processing of measurement data.

STUDENTS 'TEACHING OBLIGATIONS AND THEIR PERFORMANCE
Students are required to attend lectures.
Students are required to do 7 lab exercises.
Students are required to access knowledge tests and colloquia.

CONDITIONS FOR OBTAINING SIGNATURE
Regular attendance at lectures and completed and colloquial laboratory exercises.

TEACHING METHODS
Lectures and laboratory exercises
Consultations

MANNER OF EXAMINATION OF KNOWLEDGE AND EXAMINATION
Colloquium from laboratory exercises (a maximum of 3 colloquium appearances)
Two (partial) intermediate exams (numerical tasks for exemption from the calculation part of the exam)
Written exam (3 numerical tasks, 50% of points required for passing, with the condition of one completely correctly solved task)
Oral exam: mandatory

MONITORING OF THE COURSE QUALITY AND SUCCESSFULNESS:
Student opinion surveys

METHODOLOGICAL PREREQUISITES:
Prerequisites for enrollment are:
Physical Chemistry I (143478) - passed
Mathematics I (31901) passed
Mathematics II (21180) passed
General Chemistry (21170) passed
Inorganic Chemistry (21188) passed
Physical Chemistry I (143478) - listened to

Prerequisite for taking the course
Passed Mathematics I (31901), Mathematics II (21180), General Chemistry (21170) Physical Chemistry I (143478

LEARNING OUTCOMES
1. Describe the basic laws of physical chemistry relating to chemical equilibrium, surface phenomena of adsorption and surface tension, electrochemical equilibria (homogeneous and heterogeneous) and chemical kinetics and identify and apply them in describing the behavior of physicochemical systems
2. Apply basic knowledge of mathematics and derive equations (which clearly describe the physical phenomena under consideration)
3. Prepare and perform laboratory experiments
4. Analyze and interpret the results of the experiment
5. Prepare laboratory reports independently

LEARNING OUTCOMES AT THE PROGRAMME LEVEL:
1. explain scientific principles important for materials science and engineering, especially in chemistry, physics, mathematics and chemical engineering
2. recognise major elements of materials science and engineering: structure, properties, processing and performance of materials
3. describe different types of materials (in particular mineral binders, ceramics, polymers, metals and alloys), their application and technologies of their processing
4. relate gained knowledge of materials, their application and processing
5. gather information from various sources
6. define simple problems in area of materials science and engineering in order to solve them
7. calculate solutions to problems by correct use of physical units and thermodynamic tables
8. analyse materials using chemical and physical techniques and various laboratory equipment and instruments
9. use suitable computer databases, analytical and modelling software
10. theoretically explain result of experimental work
11. organise efficient laboratory work, whether independently or as a part of a multidisciplinary team
12. optimise chemical and other industrial processes applying chemical engineering methodology
13. use adequate models and equipment in processing, characterization and application of materials, taking into account work safety
14. present results of their work in written and oral form
15. develop work ethics, personal responsibility and aspiration for further learning
Learning outcomes:
  1. Describe the basic laws of physical chemistry relating to chemical equilibrium, surface phenomena of adsorption and surface tension, electrochemical equilibria (homogeneous and heterogeneous) and chemical kinetics and identify and apply them in describing the behavior of physicochemical systema
  2. Apply basic knowledge of mathematics and derive equations (which clearly describe the physical phenomena under consideration
  3. Prepare and perform laboratory experiments
  4. Analyze and interpret the results of the experiment
  5. Prepare laboratory reports independently
Literature:
  1. Atkin's Physical Chemistry, P. Atkins, J. de Paula, Oxford University Press, Oxfor, 2010.
  2. Osnove fizikalne kemije, R. Brdička, Školska knjiga, Zagreb,, 1969.
  3. Physical Chemistry, W. J. Moore, Longman group Ltd, London, 1974.
Prerequisit for:
Enrollment :
Passed : Calculus I
Passed : Calculus II
Attended : Inorganic chemistry
Attended : Physical chemistry I

Examination :
Passed : Calculus I
Passed : Calculus II
Passed : General chemistry
Passed : Physical chemistry I
4. semester
Mandatory course - Regular studij - Materials Science and Engineering
Consultations schedule:
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